吡蚜酮镍及铜配合物的合成、晶体结构与电催化性能研究

以吡蚜酮为配体合成了单核的镍配合物[Ni(L)2(Ac)2(H2O)2]·4H2O(1)和双核的铜配合物[Cu2(L)2(Ac)4]·2H2O(2)(L=吡蚜酮),并对化合物进行了元素分析、红外、热重、X射线衍射、循环伏安等分析。X-射线单晶衍射仪分析表明:化合物1属于三斜晶系,P1空间群,镍离子采用六配位的变形八面体几何构型。化合物2属于单斜晶系,P21/c空间群,两个醋酸根桥连相邻的Cu(Ⅱ)离子形成了双核结构。电催化实验发现化合物1和2对H2O2具有明显的电催化活性。     

Synthesis and properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/chitin nanocrystals composite scaffolds for tissue engineering

Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)/chitin nanocrystals (CNC) composite scaffolds were synthesized by the salt leaching and thermally induced phase separation (TIPS) technique. The scaffolds have porous structures with macro-pores (100-300 mm in diameters) and micro-pores (10 mm). The surface characteristics of the scaffolds were characterized by X-ray photoelectron spectroscopy (XPS) and static water contact angle measurement, and the mechanical properties were investigated by a compression test. Human adipose-derived stem cells (hADSCs) were seeded onto the PHBV/CNC scaffolds and in vitro cell culture results showed that the composite scaffolds enhanced the hADSCs adhesion, which implies that the material may have potential application in tissue engineering.     

Approximating fixed points of a pair of contractive type mappings in generalized convex metric spaces

In this paper, we consider an Ishikawa type iteration process with errors, which converges to the unique common fixed point of a pair of contractive type mappings in complete generalized convex metric spaces. Furthermore, we obtain the corresponding results in Banach spaces. Our results extend and generalize many known results.     

Synthesis and Crystal Structure of a Tetranuclear Cu（Ⅰ） Complex with Vinylidenebis（diphenylphosphine）

The vinylidenebis（diphenylphosphine） （vdpp） reacts with CuBr to give a tetranuclear complex, [Cu4（μ3-Br）2（μ2-Br）2（μ2-vdpp）2（CH3CN）2]·（CH3CN）2 1. The title complex has crystallo- graphically imposed centrosymmetry and presents a CuaBr4 core with distorted stair-like structure. All copper（I） atoms in 1 assume distorted tetrahedral coordination geometry. The distance of 2.7745（11） A between the two copper centers indicates the presence of ligand-supported Cu…Cu interactions. Crystal data for 1： C_60H_56Br_4Cu_4N_4P_4, Mr= 1530.77, triclinic, space group P1, a = 11.6593（9）, b = 11.7181（9）, c = 13.8711（11） А, a = 110.1020（10）, β = 102.0050（10）, γ = 109.8040（10）°, V = 1557.5（2） А^3, Z = 1, Dc = 1.632 g/cm^3, F（000） = 760, λ= 0.71073А, T = 298（2） K, 2θmax = 50.04°,μ= 4.056 mm^-1, S = 1.181, R = 0.0507 and wR = 0.1025.     

Synthesis and Crystal Structure of a One-dimensional Mn（Ⅱ） Coordination Polymer with 1,3-bis（4-pyridyl）propane

A new 1D zigzag chain coordination polymer, { [Mn（bpp）（bac）2]·（CHaCN）}n 1 （bpp = 1,3-bis（4-pyridyl）propane, Hbac = benzoylacetone）, has been synthesized and characterized by FT-IR spectroscopy, thermal analysis and X-ray single-crystal diffraction. In the molecular structure, all Mn atoms locate in an octahedral geometry. The guest CH3CN molecules are included in the 1D channels of the 3D packing structure of 1. Crystal data： C35H35MnNaO4, Mr = 616.60, monoclinic, space group P211c, a = 17.691（4）, b = 18,955（4）, c = 9.712（6） A, β = 93.91（3）°, V = 3249.31（1） A^3, Z = 4, Dc = 1.260 g/cm^3, F（000） = 1292, 20max = 54.9°, μ = 0.447 mm^-1, the final S = 1.020, R = 0.0693 and wR = 0.1497.     

Novel reliability-based optimization method for thermal structure with hybrid random,interval and fuzzy parameters

In this paper, novel reliability-based optimization model and method are proposed for thermal structure design with random, interval and fuzzy uncertainties in material properties, external loads and boundary conditions. Random variables are used to quantify the probabilistic uncertainty with sufficient sample data; whereas, interval variables and fuzzy variables are adopted to model the non-probabilistic uncertainty associated with objective limited information and subjective expert opinions, respectively. Using the interval ranking strategy, the level-cut limit state function is precisely quantified to represent the safety state. The eventual safety possibility is derived based on multiple integral, where the cut levels of different fuzzy variables are considered to be independent. Then a hybrid reliability-based optimization model is established with considerable computational cost caused by three-layer nested loop. To improve the computational efficiency, a subinterval vertex method is presented to replace the inner-loop and middle-loop. Comparing numerical results with traditional reliability model, a mono-objective example and a multi-objective example are provided to demonstrate the feasibility of proposed method for hybrid reliability analysis and optimization in practical engineering.     

定子表面织构对超声电机性能的影响

针对超声电机摩擦材料磨损严重和温升高的问题，采用在定子表面加工微织构的方法，提高了电机机械特性并降低了摩擦材料磨损. 首先，用显微镜测量超声电机定子表面摩擦材料黏着区域，设计出三种不同密度的凹坑织构，采用激光的方法加工在定子表面；然后，测试超声电机负载特性、效率特性和温升特性并观察定子表面. 结果表明:3-凹坑织构定子电机空载转速最高，相比光滑定子电机高出12.1%，5-凹坑织构定子电机堵转转矩和最大效率最高，分别高于光滑定子电机13.04%和17.1%，同时电机的温升也有所降低. 通过观察定子表面发现，凹坑织构有大幅降低摩擦材料黏着的作用，这种作用可以增加电机接触界面能量转换效率，提高了电机的性能并降低了摩擦材料的磨损.      

A model for prediction of minimum coating thickness in high speed slot coating

A slot coating process has been recently applied to the production of electric circuits due to its fast production rate and low cost. The prediction of minimum coating thickness or coating stability has been performed by using a viscocapillary model. However, the results are inaccurate for a high speed coating because it neglects inertia effects arising in the high speed coating condition. Thus, we modified the viscocapillary model to propose an inertia-capillary model that includes the inertial effects. As a result, this new model can be applicable to a Reynolds number of an order higher than the viscocapillary model.     

Simultaneous determination of phthalates and adipates in human serum using gas chromatography–mass spectrometry with solid‐phase extraction

A gas chromatography–mass spectrometry assay was developed and validated for the simultaneous determination of phthalates and adipates in human serum. The phthalates and adipates studied were dimethyl phthalate, diethyl phthalate, dibutyl phthalate, benzylbutyl phthalate, di‐2‐ethylhexyl phthalate, di‐n‐octyl phthalate, diethyl adipate, dibutyl adipate, diisobutyl adipate, bis(2‐butoxyethyl) adipate and di‐2‐ethylhexyl adipate, with diisooctyl phthalate as internal standard. The extraction and cleaning up procedure was carried out with solid‐phase extraction cartridges containing dimethyl butylamine groups, which showed extraction efficiencies over 88% for each analyte and the internal standard. The calibration curves obtained were linear with correlation coefficients greater than 0.98. For all analytes, the assay gave CV% values for intra‐day precision from 4.9 to 13.3% and mean accuracy values from 91.4 to 108.4%, while inter‐day precision was 5.2–13.4% and mean accuracy 91.0–110.2%. The limits of detection for the assay of phthalates and adipates were in the range 0.7–4.5 ng/mL. The method is simple, sensitive and accurate, and allows for simultaneous determination of nanogram levels of phthalates and adipates in human serum. It was successfully applied to an investigation on the level of phthalates and adipates in a non‐occupationally exposed population.     

最优(24u,{3,4},1,{2/3,1/3})光正交码

Variable-weight optical orthogonal codes(OOCs) were introduced by G. C. YANG for multimedia optical CDMA systems with multiple quality of service(Qo S) requirements. In this paper, some infinite classes of optimal cyclic packing are presented. Optimal(24u, {3, 4}, 1,{2/3, 1/3})-OOCs for any positive integer u > 1 are established.